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Equilibrium constants to have aqueous Pd(II)-chloride buildings had been obtained from Tagirov et al. (2013) and you can Pt away from Tagirov et al. (2019). The information to possess good Pd stages, hydroxide-, and oxide-buildings had been computed inside SUPCRT92 (Johnson et al., 1992) using the slop07 database with totally free times study of Sassani and Shock (1998). Analysis to have aqueous Ni varieties were obtained of Uv-Apparent spectroscopic tests for the Ni(II)-chloride complexation (Liu et al., 2012). Copper-chloride, Co-chloride complexes, and you may strong Cu mineral phase have been extracted from the newest SUPCRT databases. Some of the experimentally computed balance constants used have been extrapolated to highest temperature from the regression of your own constants facing mutual temperature. The fresh modified and you may extrapolated harmony constants and you will responses found in the newest thermodynamic model are listed in Dining table step one.

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Legitimate fresh study on the solubility out of PdS2 unfortuitously do not can be found (Dish and Wood, 1994), therefore we tentatively allow stage PdS to depict an excellent Pd part within the pyrite. The newest monzonite, since the already mapped during the depth, is short for merely 0.01 km3 of magma. Mass harmony computations having fun with Pd tonnages (23–40 t) show that −1 km3 out of magma is required to create the complete amount of Pd on the deposit for a great magma that has 10 ppb Pd. Odds are the new PGE-impact liquids was raised out of breadth, maybe acquired away from root Metal Cover-up magmas, exploiting pre-mineralization put-measure structures and you can had been restricted on the southern avoid from the clinging wall surface fault and you will picrite. Later on drinks acted in order to remobilize and you will precipitate Pd inside brief, high-degrees pouches unrelated so you can number one Cu and you will Bien au mineralization (Classification 2 examples).

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